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Record W1982304578 · doi:10.1063/1.2409930

Theoretical approach to evaluate thermodiffusion in aqueous alkanol solutions

2007· article· en· W1982304578 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueThe Journal of Chemical Physics · 2007
Typearticle
Languageen
FieldEngineering
TopicField-Flow Fractionation Techniques
Canadian institutionsToronto Metropolitan UniversityUniversity of Toronto
FundersCanadian Space Agency
KeywordsIconCitationInformation retrievalComputer scienceDownloadCitation databaseFilter (signal processing)PublishingWorld Wide WebChemistryArtLiterature

Abstract

fetched live from OpenAlex

Flow due to thermodiffusion may change direction in fluid mixtures with the variation of composition and temperature. This occurrence remains an unraveled phenomenon in petroleum research. Using a modified theoretical approach, this paper evaluates the thermal diffusion factor in alkanol water mixtures, including methanol, ethanol, and isopropanol aqueous mixtures. By combining this approach with an equation of state perturbed chain statistical associating fluid theory and using two adjustable parameters calculated from experimental data, the present approach provides a good agreement for the prediction of thermal diffusion in alkanol water mixtures when compared with the available experimental data. This work reveals that the thermodiffusion in infinite dilutions may play an important role in understanding the thermodiffusion phenomena.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.374
Threshold uncertainty score0.249

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.252
Teacher spread0.237 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it