Remote Hydrogen Plasma Chemical Vapor Deposition from (Dimethylsilyl)(trimethylsilyl)methane. 1. Kinetics of the Process; Chemical and Morphological Structure of Deposited Silicon−Carbon Films
Bibliographic record
Abstract
Amorphous hydrogenated silicon−carbon (a-Si:C:H) films have been produced by the remote hydrogen plasma chemical vapor deposition (RHP-CVD) using (dimethylsilyl)(trimethylsilyl)methane as a single-source compound. The effect of the substrate temperature on the kinetics of the RHP-CVD process, structure, composition, and surface morphology of the resulting film has been investigated. The Arrhenius plots of substrate temperature dependencies of the mass- and thickness-based film growth rate imply that the investigated RHP-CVD is an adsorption-controlled process. The increase of the substrate temperature from 30 to 400 °C causes the elimination of organic moieties from the film and the formation of a Si-carbidic network structure. The microscopic examination revealed that the films are defect-free materials of excellent morphological homogeneity and good conformality of coverage.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.001 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".