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Record W1982757943 · doi:10.1021/om2007979

A Polyboryl-Functionalized Triazine as an Electron Transport Material for OLEDs

2011· article· en· W1982757943 on OpenAlexafffund
Christina Sun, Zachary M. Hudson, Michael G. Helander, Zheng‐Hong Lu, Suning Wang

Bibliographic record

VenueOrganometallics · 2011
Typearticle
Languageen
FieldEngineering
TopicOrganic Light-Emitting Diodes Research
Canadian institutionsUniversity of TorontoQueen's University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsOLEDChemistryPhosphorescenceHOMO/LUMOCommon emitterTriazineMoleculePhotochemistryElectronElectron transport chainOptoelectronicsPolymer chemistryMaterials scienceFluorescenceOrganic chemistryPhysicsOptics

Abstract

fetched live from OpenAlex

A new pinwheel-like triazine molecule functionalized by three BMes 2 ( m -Ph) groups ( B3T ) has been synthesized and fully characterized. This molecule has been found to have a low LUMO ( E a = 3.25 eV) and a deep HOMO (6.73 eV) energy level with a high triplet energy level (3.07 eV) and is thus very promising as an electron transport material for phosphorescent OLEDs. Preliminary studies show that B3T is indeed a very effective electron transport material for OLEDs where the green phosphorescent compound Ir(ppy) 2 (acac) is used as the emitter.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.056
Threshold uncertainty score0.997

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0080.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.024
GPT teacher head0.249
Teacher spread0.226 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations60
Published2011
Admission routes2
Has abstractyes

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