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Record W1982794997 · doi:10.1021/ie8019938

Safe-Parking of a Styrene Polymerization Process

2009· article· en· W1982794997 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
fundA Canadian funder is recorded on the work.

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2009
Typearticle
Languageen
FieldEngineering
TopicAdvanced Control Systems Optimization
Canadian institutionsMcMaster University
FundersNatural Sciences and Engineering Research Council of CanadaMcMaster University
KeywordsControl theory (sociology)RectificationComputer scienceFault (geology)Process (computing)Controller (irrigation)ActuatorStyreneModel predictive controlControl engineeringControl (management)EngineeringMaterials science

Abstract

fetched live from OpenAlex

This work considers the problem of control and fault-handling in living nitroxide-mediated radical polymerization (NMRP) of styrene subject to input constraints. First, a Lyapunov based model predictive controller is designed that allows for an explicit computation of the stability region. Next, a fault in one of the monomer feed streams is considered due to which operation of the reactor at the nominal operating point is no longer possible. It is shown that trying to continue nominal operation using the remaining functioning actuator drives the process to a point resulting in significantly off-spec product. A safe-parking framework is utilized to choose an operating point during fault rectification so that the styrene produced during fault rectification complies with the desired product specifications, and smooth resumption of nominal operation upon fault rectification is achieved.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.242
Threshold uncertainty score0.838

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.042
GPT teacher head0.311
Teacher spread0.269 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it