Coupled Electronic States in <i>trans</i>-Dioxo Complexes of Rhenium(V) and Osmium(VI) Probed by Near-Infrared and Visible Luminescence Spectroscopy
Bibliographic record
Abstract
trans -Dioxo complexes of rhenium(V) and osmium(VI) with ethylenediamine, imidazole, and oxalate ancillary ligands show luminescence maxima varying between 620 and 900 nm. The resolved vibronic progressions of the rhenium complexes have intensity distributions that cannot be rationalized with harmonic potential energy surfaces. The broadband spectra of the osmium(VI) complexes also show deviations from the band shapes expected for a harmonic ground-state potential surface. We use the large variation of luminescence energies and the vibronic features to show the influence of excited electronic states on the ground-state potential energy surface. The vibronic structure and band envelopes of the luminescence spectra are calculated using the lowest energy adiabatic surface obtained from three interacting electronic states.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".