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Record W1983835726 · doi:10.1002/chem.201490099

Cover Picture: Asymmetric Synthesis of Fortucine and Reassignment of Its Absolute Configuration (Chem. Eur. J. 25/2014)

2014· paratext· en· W1983835726 on OpenAlexaff
Marc‐André Beaulieu, Xavier Ottenwaelder, Sylvain Canesi

Bibliographic record

VenueChemistry - A European Journal · 2014
Typeparatext
Languageen
FieldBiochemistry, Genetics and Molecular Biology
TopicChemical Synthesis and Analysis
Canadian institutionsConcordia UniversityUniversité du Québec à Montréal
Fundersnot available
KeywordsAnalogyCover (algebra)MythologyAbsolute configurationNatural productProduct (mathematics)ChemistryFace (sociological concept)Computer scienceStereochemistryMathematicsPhilosophyArtLiteratureEpistemologyEngineeringLinguisticsGeometry

Abstract

fetched live from OpenAlex

According to Greek mythology the species of plant Fortune Narcissus of Amarillydaceaes (shown on the right side of the cover illustration) grew exactly where Narcissus drowned while he was admiring his own reflection (or his mirror image) in the water. This story serves as an appropriate analogy for the synthesis of the mirror image of fortucine, a bioactive product isolated from the leaves of this plant, in that the presented asymmetric synthesis has allowed the reassignment of the absolute configuration of the natural product as presented on the top face of the cover. See the Communication by S. Canesi and co-workers for more details.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Other · Consensus signal: Other
Teacher disagreement score0.063
Threshold uncertainty score0.212

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.001
Science and technology studies0.0010.000
Scholarly communication0.0010.002
Open science0.0010.001
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.0630.013

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.008
GPT teacher head0.218
Teacher spread0.210 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designNot applicable
Domainnot available
GenreOther

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2014
Admission routes1
Has abstractyes

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