Luminescence degradation in phosphorescent organic light-emitting devices by hole space charges
Bibliographic record
Abstract
We studied electroluminescence degradation in phosphorescent organic light-emitting devices (PHOLEDs) and found that two distinctive mechanisms are responsible for device degradation depending on the device structure. For a device without a hole blocking layer (HBL), excess holes penetrate into the electron transport layer (ETL) and lead to the deterioration of the ETL adjacent to the interface of the emitting layer. The lower electron transport capacity of the degraded ETL alters the balance in hole/electron injection into the emitting layer and results in a decrease in the luminescence efficiency of the PHOLEDs. For a device with a HBL, on the other hand, holes accumulate and become trapped in the emitting layer, and result in a decrease in the luminescence efficiency of the PHOLEDs, likely due to their role in acting as exciton quenchers or as nonradiative charge recombination centers.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".