ABC triblock copolymer hamburger-like micelles, segmented cylinders, and Janus particles
Why this work is in the frame
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Bibliographic record
Abstract
An ABC linear triblock copolymer with a carboxyl-containing terminal C block and a photocrosslinkable middle B block was synthesized and characterized. In a poor solvent for the B block and in the presence of a diamine, (−)-sparteine, which complexed with the C block and made it insoluble, the triblock copolymer self-assembled into hamburger-like micellar aggregates and segmented cylinders. In a “hamburger”, the “buns” were made of the B block, the filling was made of the complexed C block, and the soluble A chains stretched out from the bun surface into the solvent phase. The main body of the segmented cylinders was made of stacking alternating B and C stubs. The cylinders were dispersed in solvent by the A chains stretching out from the surfaces of the B stubs. After the photocrosslinking of the buns of the hamburgers and the removal of (−)-sparteine by dialysis, we were able to separate the buns of the hamburgers to yield presumably Janus particles.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.006 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it