Laser-induced breakdown spectroscopy: investigation of Pb resonant excitation and decay paths
Bibliographic record
Abstract
A promising way of improving the sensitivity of the LIBS (Laser-Induced Breakdown Spectroscopy) technique consists in using basically two successive laser pulses instead of only one as in conventional LIBS: the first pulse generates the plasma and the second pulse selectively excites a specific quantum level of a given trace atomic species inside the plasma. The effect of this second laser pulse is to increase the emission of the atomic species of interest and therefore enhance the signal-to-noise ratio, leading to an improved detection. As a first step toward the detection of Pb in various materials, we present in this work a study of the resonant excitation and decay paths of Pb atoms in a laser-produced plasma. The ablation was performed using a Nd:YAG laser and the 2<sup>nd</sup> pulse provided by an Optical Parametric Oscillator (OPO) laser was launched several μs afterwards.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".