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Record W1986231616 · doi:10.1524/zpch.2009.6027

Theoretical Approaches to Surface Kinetics: A Perspective

2009· article· en· W1986231616 on OpenAlexfundno aff
Hans Juergen Kreuzer

Bibliographic record

VenueZeitschrift für Physikalische Chemie · 2009
Typearticle
Languageen
FieldEarth and Planetary Sciences
Topicnanoparticles nucleation surface interactions
Canadian institutionsnot available
FundersOffice of Naval ResearchNatural Sciences and Engineering Research Council of Canada
KeywordsNon-equilibrium thermodynamicsMesoscopic physicsStatistical physicsScope (computer science)SophisticationPerspective (graphical)HierarchyDetailed balanceSurface (topology)Theoretical physicsPhysicsThermodynamicsComputer scienceMathematicsEconomicsQuantum mechanicsSociology

Abstract

fetched live from OpenAlex

Abstract In this paper I outline the scope and success of the theory of equilibrium and nonequilibrium properties of surfaces and adsorbates Basic issues such as time and length scales lead to various levels of sophistication provided the proper assumptions are implimented successfully leading to a hierarchy of theories from the macroscopic level of nonequilibrium thermodynamics to Markov processes at the mesoscopic level and ultimately to a fully quantum mechanical description. Special ttention will be given to the role of detailed balance in sticking and desorption via direct and precursor-dominated channels.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.558
Threshold uncertainty score0.998

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0050.003

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.043
GPT teacher head0.267
Teacher spread0.223 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2009
Admission routes1
Has abstractyes

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