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XANES and XEOL studies of Eu-doped calcium tungstate in silica synthesized by sol-gel method

2009· article· en· W1986823885 on OpenAlexaff
J. Y. Peter Ko, Yongfeng Hu, Lidia Armelao, Tsun‐Kong Sham

Bibliographic record

VenueJournal of Physics Conference Series · 2009
Typearticle
Languageen
FieldMaterials Science
TopicLuminescence Properties of Advanced Materials
Canadian institutionsCanadian Light Source (Canada)University of SaskatchewanWestern University
Fundersnot available
KeywordsXANESLuminescenceEuropiumTungstateMaterials scienceDopingAbsorption (acoustics)Inorganic chemistryAnalytical Chemistry (journal)ChemistrySpectroscopyMetallurgyOptoelectronicsComposite materialOrganic chemistry

Abstract

fetched live from OpenAlex

Europium-doped calcium tungstate (CaWO4:Eu) was synthesized by a modified Pechini method. X-ray absorption near-edge structure (XANES) and X-ray excited optical luminescence (XEOL) was employed to probe the chemical and luminescence properties of CaWO4:Eu. XANES results demonstrate that the chemical environment around calcium in the doped CaWO4 is similar to that of undoped CaWO4. On the other hand, chemical environment around oxygen is very different. Moreover, the results suggest that contributions to luminescence in the sample are from both silica (from silica matrix) and CaWO4. Using XEOL, luminescence pathways and efficiency associated with the system can be identified.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.015
Threshold uncertainty score0.752

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.049
GPT teacher head0.334
Teacher spread0.285 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations4
Published2009
Admission routes1
Has abstractyes

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