Localized relaxation’s strength and its mimicry of glass-softening thermodynamics
Why this work is in the frame
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Bibliographic record
Abstract
The dielectric relaxation strength of the β process, Δεβ, in a rigid-molecular glass of 16.6 mol % chlorobenzene cis-decalin mixture increases slowly with temperature, T, until the glass-softening range is reached, and thereafter it increases rapidly, i.e., (dΔεβ/dT) increases at Tg relatively abruptly. This is remarkably similar to the volume and entropy against T plots of a glass being heated through its Tg and of the implied rise in the expansion coefficient and heat capacity near Tg. The β-relaxation rate increases smoothly through Tg according to the Arrhenius equation, and the distribution of relaxation times becomes narrower. Both the entropy and free volume affect Δεβ, but not the rate.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it