Selective Synthesis and Formation Mechanism of TiS<sub>2</sub> Dendritic Crystals
Bibliographic record
Abstract
High-purity TiS 2 dendritic crystals have been selectively synthesized via an easy and simple CVT (chemical vapor transport) process using only inorganic reagents. Reaction temperature and duration are the most important factors controlling the morphologies of TiS 2 dendrites. Instead of using organic reagents as templates to induce the self-assembly of inorganic molecules, a simple CVT process was adopted to realize the hierarchical self-assembly of inorganic molecules via transport in a sulfur-rich atmosphere far from thermodynamic equilibrium conditions. The phase structures and morphologies of the TiS 2 products were characterized by XRD, polarized-light microscopy, SEM, and TEM. All microscopic observations not only indicate a dendritic morphology but also provide direct evidence for the growth process of TiS 2 dendrites. The formation mechanism for TiS 2 fractals is further investigated and discussed on the basis of the experimental results.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".