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Record W1988345246 · doi:10.1021/cg100469x

Toward Nanoscale Engineering of Triacylglycerol Crystal Networks

2010· article· en· W1988345246 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueCrystal Growth & Design · 2010
Typearticle
Languageen
FieldAgricultural and Biological Sciences
TopicFood Chemistry and Fat Analysis
Canadian institutionsUniversity of Guelph
Fundersnot available
KeywordsCrystallizationSupersaturationNanoscopic scaleChemical engineeringMaterials scienceCrystal (programming language)Mass fractionTransmission electron microscopyNanostructureShear rateChemistryNanotechnologyComposite materialRheologyOrganic chemistry

Abstract

fetched live from OpenAlex

Cryogenic transmission electron microscopy and X-ray diffraction techniques were used to analyze the effect of crystallization conditions on the nanostructure of triacylglycerol crystal networks. Nanoplatelet size was strongly affected by composition and degree of supersaturation in the melt, as well as external fields during crystallization, such as cooling and shear rate. Chemical interesterification induced a decrease in nanoplatelet size, while increases in the solid mass fraction also resulted in a decrease in nanoplatelet dimensions. Fast cooling rates and crystallization under shear produced a significant decrease in platelet length, width, and thickness. This work opens up the possibility of judiciously engineering the nanoscale of fat-structured products in order to formulate products with specific functionalities including hardness, liquid oil binding, water vapor barrier properties, and metabolic response in humans.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.034
Threshold uncertainty score0.363

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.185
Teacher spread0.168 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it