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Record W1988694164 · doi:10.4236/wjet.2014.24032

Optimization of an Ammonia Synthesis Converter

2014· article· en· W1988694164 on OpenAlexaff
Jackson Gunorubon Akpa, Nwokoma Raphael Raphael

Bibliographic record

VenueWorld Journal of Engineering and Technology · 2014
Typearticle
Languageen
FieldChemical Engineering
TopicAmmonia Synthesis and Nitrogen Reduction
Canadian institutionsNatural Resources Canada
Fundersnot available
KeywordsCatalysisAmmoniaAmmonia productionCatalytic converterInletHydrogenNitrogenChemistryMaterials scienceChemical engineeringThermodynamicsMathematicsEngineeringOrganic chemistryPhysicsMechanical engineering

Abstract

fetched live from OpenAlex

A scheme that optimizes the converter of an ammonia synthesis plant to determine optimal inlet temperatures of the catalyst beds has been developed. The optimizer maximizes an objective function—The fractional conversion of nitrogen on the four catalyst beds of the converter subject to variation of the inlet temperature to each catalyst bed. An iterative procedure was used to update the initial values of inlet temperature thus ensuring accurate results and quick convergence. Converter model results obtained with optimized operating conditions showed significant increase in fractional conversion of 42.38% (from 0.1949 to 0.2586), increased rate of reaction evident in a 13.18% (0.5317 to 0.4616) and 23.84% (0.1946 to 0.1482) reduction in reactants (hydrogen and nitrogen) concentration respectively and a 56.48% increase (from 0.1181 to 0.1838) in ammonia concentration at the end of the fourth catalyst bed compared to results obtained with industrial operating conditions.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Methods · Consensus signal: Methods
Teacher disagreement score0.004
Threshold uncertainty score0.007

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0010.000
Scholarly communication0.0010.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.184
Teacher spread0.180 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreMethods

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations15
Published2014
Admission routes1
Has abstractyes

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Same venueWorld Journal of Engineering and TechnologySame topicAmmonia Synthesis and Nitrogen ReductionFrench-language works237,207