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Record W1988888032 · doi:10.1002/qua.21143

Hopping kinetics on a finite 1D chain: An exact analysis

2006· article· en· W1988888032 on OpenAlexafffund
Jean‐Sabin McEwen, S.H. Payne, H. J. Kreuzer, Christian Bracher

Bibliographic record

VenueInternational Journal of Quantum Chemistry · 2006
Typearticle
Languageen
FieldPhysics and Astronomy
TopicSpectroscopy and Quantum Chemical Studies
Canadian institutionsDalhousie University
FundersKillam TrustsAlexander von Humboldt-Stiftung
KeywordsEigenvalues and eigenvectorsLattice (music)Statistical physicsPosition and momentum spaceMomentum (technical analysis)Chain (unit)QuantumWork (physics)Boundary value problemKinetic energyPhysicsPeriodic boundary conditionsk-nearest neighbors algorithmDiffusionQuantum mechanics

Abstract

fetched live from OpenAlex

Abstract In the present study, we develop a kinetic lattice gas model for hopping in an inhomogeneous one‐dimensional adsorbate system with nearest‐neighbor interactions and periodic boundary conditions. From the matrices of the associated equations of motion, we can calculate adsorbate correlation functions in momentum space exactly on all time and length scales. The corresponding eigenvalues and eigenvectors in the long‐time, long‐wavelength limit yield the diffusion coefficient. We analyze its dependence on coverage and temperature and compare our results with earlier analytic work for this model. Our approach is readily extendable to two‐dimensional systems. © 2006 Wiley Periodicals, Inc. Int J Quantum Chem, 2006

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.077
Threshold uncertainty score0.639

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.280
Teacher spread0.269 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations5
Published2006
Admission routes2
Has abstractyes

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