Metal–Chalcogenolate Complexes with Silyl Functionalities: Synthesis and Reaction Chemistry
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Bibliographic record
Abstract
Abstract Metal complexes with reactive [ESiR 3 ] − (E = S, Se, Te) or [S(SiMe 2 )] 2− ligands provide a means for the delivery of {ME n } m− units in the formation of heterometallic polynuclear complexes and clusters. These complexes can be reacted with M′ salts to promote M–E–M′ interactions via the elimination of a silane side product. This research report summarizes the recent developments in the synthesis of silylchalcogenolate complexes of the d ‐block metals with emphasis directed to those for which reactivity studies for the formation of ternary clusters have been carried out. The effects of varying the groups on the silyl moiety on the stability and reactivity of these precursor molecules are also discussed.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.012 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it