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Record W1989212275 · doi:10.1002/prs.11741

Analysis of a blast due to inadvertant mixing of ammonium sulfate and sodium hyplochlorite

2015· article· en· W1989212275 on OpenAlexaboutno aff
Graeme W. Norval

Bibliographic record

VenueProcess Safety Progress · 2015
Typearticle
Languageen
FieldEnvironmental Science
TopicWater Treatment and Disinfection
Canadian institutionsnot available
Fundersnot available
KeywordsChloramineSodium hypochloriteChlorineChemical industryMixing (physics)AmmoniaWaste managementChemistrySulfateSodium sulfateHypochloriteEnvironmental scienceAmmonium sulfatePulp and paper industryEnvironmental chemistryEnvironmental engineeringSodiumEngineeringInorganic chemistryOrganic chemistry

Abstract

fetched live from OpenAlex

Ammonium sulfate and sodium hypochlorite are common industrial chemicals, often used together in water treatment. The consequences of mixing hypochlorite (chlorine) solution with ammonia solutions are well understood within the chlorine industry; detonable chloramines are produced. This knowledge is not well known in other industries; fortunately, few locations have both chemicals on site. These products were inadvertently mixed, resulting in an explosion, at a water treatment facility in Kitchener, Ontario on April 2, 2014. The chemistry of the incident is presented and discussed. Facilities that handle both chemicals, such as the water treatment industry need to have heightened sense of understanding of this particular reactive chemical hazard. © 2015 American Institute of Chemical Engineers Process Saf Prog 35: 92–95, 2016

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Case report · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.004
Threshold uncertainty score0.008

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.001
Science and technology studies0.0010.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.249
Teacher spread0.237 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designCase report
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations3
Published2015
Admission routes1
Has abstractyes

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