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Record W1989363680 · doi:10.1002/cjce.5450820528

A Novel Photometric Technique to Detect the Onset of Asphaltene Precipitation at Low Concentrations: The Effect of Maltenes and Water

2004· article· en· W1989363680 on OpenAlexafffundvenue
Géza Horváth‐Szabó, Jacob H. Masliyah, Jan Czarnecki

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2004
Typearticle
Languageen
FieldChemistry
TopicPetroleum Processing and Analysis
Canadian institutionsSyncrude (Canada)University of Alberta
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsAsphalteneHeptaneToluenePrecipitationChemistryFlocculationIntensity (physics)PhotometerOrganic chemistryMeteorologyOptics

Abstract

fetched live from OpenAlex

Abstract A photometer was utilized to measure the intensity of scattered light in toluene / heptane / asphaltenes mixtures. On the scattering‐intensity versus heptane‐to‐toluene ratio functions, two linear regions can be observed. The intersection of these regions determines the heptane‐to‐toluene ratio at which the precipitation of asphaltenes starts. The onset of asphaltene precipitation was determined as a function of asphaltene concentration in the presence and in the absence of maltenes as well as water. The onset is dependent on the asphaltene concentration. The presence of water promoted while the presence of maltenes inhibited the precipitation of asphaltenes.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0010.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.197
Teacher spread0.193 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations8
Published2004
Admission routes3
Has abstractyes

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