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Record W1989885114 · doi:10.1080/00268970009483274

Infrared spectrum of the Ar-CO complex: observation of the <i>v</i> <sub>co</sub> = 2 ← 0 band at 4260 cm <sup>−1</sup>

2000· article· en· W1989885114 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueMolecular Physics · 2000
Typearticle
Languageen
FieldPhysics and Astronomy
TopicAdvanced Chemical Physics Studies
Canadian institutionsSteacie Institute for Molecular Sciences
Fundersnot available
KeywordsOvertonevan der Waals forceInfraredIntermolecular forceChemistryInfrared spectroscopySpectrum (functional analysis)SpectrometerAbsorption (acoustics)Atomic physicsAnalytical Chemistry (journal)Fourier transformAbsorption spectroscopyPhysicsSpectral lineMoleculeOptics

Abstract

fetched live from OpenAlex

The spectrum of the weakly-bound van der Waals complex Ar-CO has been observed for the first time in the region of the CO vibrational overtone, using a long-path (180 m) low-temperature (64 K) absorption cell and a Fourier transform infrared spectrometer. The appearance of the spectrum was very similar to that studied previously in the v co = 1 ← 0 region. However, it was very much weaker, so a detailed analysis was only possible for the relatively uncongested K = 1 ← 0 and 0 ← 1 subbands. The parameters determined here for these sub-bands should help to constrain the C-O bond length dependence of the Ar-CO intermolecular potential in future theoretical models.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.154
Threshold uncertainty score0.823

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.011
GPT teacher head0.221
Teacher spread0.210 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it