MétaCan
Menu
Back to cohort
Record W1989995741 · doi:10.1103/physrevb.91.125120

Efficient dielectric matrix calculations using the Lanczos algorithm for fast many-body<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>G</mml:mi><mml:mn>0</mml:mn></mml:msub><mml:msub><mml:mi>W</mml:mi><mml:mn>0</mml:mn></mml:msub></mml:mrow></mml:math>implementations

2015· article· lv· W1989995741 on OpenAlexafffund
Jonathan Laflamme Janssen, Bruno Rousseau, Michel Côté

Bibliographic record

VenuePhysical Review B · 2015
Typearticle
Languagelv
FieldPhysics and Astronomy
TopicSpectroscopy and Quantum Chemical Studies
Canadian institutionsUniversité de MontréalRegroupement Québécois sur les Matériaux de Pointe
FundersFonds de recherche du Québec – Nature et technologiesNatural Sciences and Engineering Research Council of Canada
KeywordsAlgorithmDielectricSpeedupConjugate gradient methodMatrix (chemical analysis)Computer scienceMathematicsPhysicsMaterials scienceQuantum mechanicsParallel computing

Abstract

fetched live from OpenAlex

We present a ${G}_{0}{W}_{0}$ implementation that assesses the two major bottlenecks of traditional plane-waves implementations, the summations over conduction states and the inversion of the dielectric matrix, without introducing new approximations in the formalism. The first bottleneck is circumvented by converting the summations into Sternheimer equations. Then, the novel avenue of expressing the dielectric matrix in a Lanczos basis is developed, which reduces the matrix size by orders of magnitude while being computationally efficient. We also develop a model dielectric operator that allows us to further reduce the size of the dielectric matrix without accuracy loss. Furthermore, we develop a scheme that reduces the numerical cost of the contour deformation technique to the level of the lightest plasmon pole model. Finally, the use of the simplified quasiminimal residual scheme in replacement of the conjugate gradients algorithm allows a direct evaluation of the ${G}_{0}{W}_{0}$ corrections at the desired real frequencies, without need for analytical continuation. The performance of the resulting ${G}_{0}{W}_{0}$ implementation is demonstrated by comparison with a traditional plane-waves implementation, which reveals a 500-fold speedup for the silane molecule. Finally, the accuracy of our ${G}_{0}{W}_{0}$ implementation is demonstrated by comparison with other ${G}_{0}{W}_{0}$ calculations and experimental results.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Scholarly communication, Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.895
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.001
Meta-epidemiology (narrow)0.0010.002
Meta-epidemiology (broad)0.0010.003
Bibliometrics0.0000.002
Science and technology studies0.0030.001
Scholarly communication0.0010.001
Open science0.0020.002
Research integrity0.0010.002
Insufficient payload (model declined to judge)0.1580.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.029
GPT teacher head0.301
Teacher spread0.272 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations23
Published2015
Admission routes2
Has abstractyes

Explore more

Same venuePhysical Review BSame topicSpectroscopy and Quantum Chemical StudiesFrench-language works237,207