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Record W1990011345 · doi:10.1002/cem.924

Mathematical improvements to maximum likelihood parallel factor analysis: experimental studies

2005· article· en· W1990011345 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal of Chemometrics · 2005
Typearticle
Languageen
FieldChemistry
TopicSpectroscopy and Chemometric Analyses
Canadian institutionsDalhousie University
Fundersnot available
KeywordsCovarianceAlgorithmComputer scienceSet (abstract data type)Covariance matrixExperimental dataData setVariety (cybernetics)StatisticsData miningMathematicsArtificial intelligence

Abstract

fetched live from OpenAlex

Abstract In this paper, the application of a number of simplified algorithms for maximum likelihood parallel factor analysis (MLPARAFAC) to experimental data is explored. The algorithms, described in a companion paper, allow the incorporation of a variety of correlated error structures into the three‐way analysis. In this work, three experimental data sets involving fluorescence excitation‐emission spectra of synthetic three‐component mixtures of aromatic compounds are used to test these algorithms. Different experimental designs were employed for the acquisition of these data sets, resulting in measurement errors that were correlated in either two or three modes. A number of data‐analysis methods were applied to characterize the error structures of these data sets. In all cases, the introduction of statistically meaningful information translated to estimates of better quality than the conventional PARAFAC estimates of concentrations and spectra. The use of the algorithms that employ the error structure suggested by the analysis of the error covariance matrix yielded the best results for each data set. Copyright © 2005 John Wiley & Sons, Ltd.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.182
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0020.006
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0030.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.039
GPT teacher head0.353
Teacher spread0.314 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it