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Record W1990259685 · doi:10.1107/s0108270100006144

(<i>o</i>-Benzoquinone diimine-<i>N</i>,<i>N</i>′)dichlorobis(triphenylphosphine-<i>P</i>)ruthenium(II) 1.33-methanol 0.33-dichloromethane solvate

2000· article· he· W1990259685 on OpenAlexaff
Diego Venegas‐Yazigi, Hameed A. Mirza, A. B. P. Lever, Alan J. Lough, Juan Costamagna, Andrés Vega, Ramón Latorre

Bibliographic record

VenueActa Crystallographica Section C Crystal Structure Communications · 2000
Typearticle
Languagehe
FieldMedicine
TopicMetal complexes synthesis and properties
Canadian institutionsUniversity of TorontoYork University
Fundersnot available
KeywordsTriphenylphosphineDiimineDichloromethaneChemistryMoleculeRutheniumOctahedronMethanolCrystal structureMedicinal chemistryCrystallographyStereochemistryOrganic chemistryCatalysisSolvent

Abstract

fetched live from OpenAlex

The Ru atom in the title compound, [RuCl(2){P(C(6)H(5))(3)}(2){C(6)H(4)(NH)(2)}].1.33CH(3)OH.0.33CH(2)Cl(2), shows a six-coordinate octahedral geometry, with a trans arrangement of the triphenylphosphine groups. One and a half molecules of complex, two molecules of methanol and a half molecule of dichloromethane form the asymmetric unit, with crystallographic twofold rotation symmetry for the complex molecule in a special position.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.001
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Science and technology studies, Research integrity, Insufficient payload (model declined to judge)
Consensus categoriesMeta-epidemiology (narrow), Science and technology studies, Research integrity
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.960
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0020.001
Meta-epidemiology (narrow)0.0030.002
Meta-epidemiology (broad)0.0030.002
Bibliometrics0.0020.006
Science and technology studies0.0050.003
Scholarly communication0.0010.001
Open science0.0050.002
Research integrity0.0020.005
Insufficient payload (model declined to judge)0.0220.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.026
GPT teacher head0.259
Teacher spread0.233 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; both teacher heads agree on what is shown here.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2000
Admission routes1
Has abstractyes

Explore more

Same venueActa Crystallographica Section C Crystal Structure CommunicationsSame topicMetal complexes synthesis and propertiesFrench-language works237,207