Diffusion-Controlled Electrosynthesis of Nanoporous Electrodes for Electrochemical Supercapacitors
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Bibliographic record
Abstract
Nanostructured manganese dioxide films were obtained by electrosynthesis using 0.02-0.15 M KMnO4 solutions. The diffusion-controlled deposition mechanism is based on the reduction of anionic MnO4- at the cathode surface. The method allowed the fabrication of porous films for application in electrochemical supercapacitors (ES). It was shown that film porosity is beneficial for the charge transfer during deposition, crack prevention in thick films and electrolyte diffusion in fabricated ES electrodes. Porous nanostructured films showed good capacitive behavior in the 0.1 M Na2SO4 electrolyte in a voltage window of 1V. The specific capacitance decreased with increasing scan rate due to the diffusion limitation in the porous manganese dioxide electrodes
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.004 | 0.002 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it