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Record W1995360044 · doi:10.1002/cjce.5450840301

Molecular Modelling—an Enabling Technology for Chemical Engineers

2006· article· en· W1995360044 on OpenAlexaffvenue
Phillip Choi

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2006
Typearticle
Languageen
FieldChemistry
TopicAdvanced Physical and Chemical Molecular Interactions
Canadian institutionsUniversity of Alberta
Fundersnot available
KeywordsPolyolefinStatistical physicsMiscibilityMolecular dynamicsScale (ratio)Monte Carlo methodSet (abstract data type)Field (mathematics)Force field (fiction)Computer scienceMixing (physics)NanotechnologyMaterials sciencePhysicsMathematicsChemistryComputational chemistryPolymerArtificial intelligence

Abstract

fetched live from OpenAlex

Abstract This article briefly describes the basic concepts involved in the two most commonly used molecular modelling methods—molecular dynamics (MD) and Monte Carlo (MC). The methods are particularly useful for studying structures at the length scale of nanometre. Two examples (both are on the study of the miscibility of polyolefin blends) are used to illustrate the techniques. It is demonstrated that it is the nano‐scaled structures formed by the segments of the constituent polyolefins that prevent them from mixing with each other. The examples also show that selection of specific method (MD or MC) depends on the nature of the problem in hand. In general, MC is more efficient than MD in terms of generating equilibrated structure while MD can provide information about the dynamics of a system. This is simply because MD requires the solution of equations of motion (a set of second order differential equations) while MC does not. Nonetheless, both methods need a reasonably accurate force field.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.002
metaresearch head score (Gemma)0.004
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: Theoretical or conceptual
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.009
Threshold uncertainty score0.030

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0020.004
Meta-epidemiology (narrow)0.0010.001
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0010.001
Science and technology studies0.0010.001
Scholarly communication0.0030.004
Open science0.0020.002
Research integrity0.0020.002
Insufficient payload (model declined to judge)0.0090.005

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.005
GPT teacher head0.193
Teacher spread0.188 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designTheoretical or conceptual
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations1
Published2006
Admission routes2
Has abstractyes

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