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Record W1996335772 · doi:10.1107/s090904951204109x

Time-resolved XAS (Bonn-SUT-SLRI) beamline at SLRI

2012· article· fr· W1996335772 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueJournal of Synchrotron Radiation · 2012
Typearticle
Languagefr
FieldPhysics and Astronomy
TopicX-ray Spectroscopy and Fluorescence Analysis
Canadian institutionsCanadian Light Source (Canada)University of Saskatchewan
FundersSynchrotron Light Research Institute
KeywordsBeamlineXANESX-ray absorption spectroscopyMonochromatorSynchrotron radiationAbsorption spectroscopySynchrotronSpectroscopyAbsorption (acoustics)OpticsMaterials scienceExtended X-ray absorption fine structureAbsorption edgeSpectral lineAnalytical Chemistry (journal)ChemistryPhysicsBeam (structure)OptoelectronicsBand gap

Abstract

fetched live from OpenAlex

An energy-dispersive X-ray absorption spectroscopy beamline has been constructed at the Synchrotron Light Research Institute, Thailand. The beamline was designed to utilize the synchrotron radiation with photon energies between 2400 and 8000 eV. The horizontal focusing of the bent crystal in the energy-dispersive monochromator offers a small polychromatic focal spot of 1 mm at the sample position. By employing an energy-dispersive scheme, the whole X-ray absorption near-edge structure (XANES) can be obtained simultaneously using a position-sensitive detector with a fastest readout speed of 25 ms. The short data collection time opens a new opportunity for time-resolved X-ray absorption spectroscopy (XAS) experiments such as studies of changes of the electronic structures or the local coordination environments of an atom during a change in thermodynamic conditions. For this purpose, an in situ cell was designed and fabricated for the beamline. Thermal oxidation of TiO(2) was chosen as an in situ experiment example. The structural change of TiO(2) as a function of temperatures was monitored from the change in the measured XAS spectra. The obtained Ti K-edge XANES spectra clearly show the formation of an anatase phase when the temperature was raised to 673 K.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesInsufficient payload (model declined to judge)
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.544
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.002
Open science0.0000.000
Research integrity0.0000.001
Insufficient payload (model declined to judge)0.0050.002

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.248
Teacher spread0.241 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it