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Record W1996491721 · doi:10.1021/ie050819r

Performance of Auto-Cyclic Reactor in Catalytic Combustion of Lean Fuel Mixtures

2005· article· en· W1996491721 on OpenAlexafffund
D. Klvana, Jamal Chaouki, Christophe Guy, Jitka Kirchnerová, Massimiliano Zanoletti

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2005
Typearticle
Languageen
FieldChemical Engineering
TopicCatalysis and Oxidation Reactions
Canadian institutionsPolytechnique Montréal
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsMethanePropaneChemistryCombustionCatalysisMethane reformerAcetoneChemical engineeringMaterials scienceOrganic chemistrySteam reforming

Abstract

fetched live from OpenAlex

This work examines the experimental assessment of the conditions required for sustainable autothermal catalytic combustion of mixtures of lean fuels (methyl ethyl ketone (MEK), acetone, propane, and methane) in a small nonadiabatic laboratory auto-cyclic reactor (ACR) loaded with a combination of laboratory-prepared monoliths and commercial palladium catalyst pellets. Despite the non-optimized physical parameters of this reactor, the experiments demonstrated that, for a given fuel, the domain of autothermal operation is dependent primarily on fuel/catalyst reactivity that, in turn, dictates the minimum heat output (power) requirement of the air/fuel mixture and, to a lesser degree, flow rate. In correlation with the reactivity of individual fuels, the power requirement for a flow rate of 64 L/min (ambient) increased, from 375 W for MEK and acetone to ∼480 W for propane and 613 W for methane. For propane and methane combusted under the limiting conditions, oscillatory behavior was observed with the periods that correlated with the power of the fuel/air mixture. When the methane/air feed mixture was heated to 400 °C before entering the ACR, sustained combustion was assured for 0.6% methane flowing at a rate of 97.2 L/min.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.003

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.055
GPT teacher head0.308
Teacher spread0.253 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations7
Published2005
Admission routes2
Has abstractyes

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