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An exactly solvable Ogston model of gel electrophoresis: VIII. Nonconducting gel fibers, curved field lines, and the Nernst-Einstein relation

2001· article· en· W1997708525 on OpenAlexaff
Jean‐François Mercier, Frédéric Tessier, Gary W. Slater

Bibliographic record

VenueElectrophoresis · 2001
Typearticle
Languageen
FieldChemistry
TopicElectrostatics and Colloid Interactions
Canadian institutionsUniversity of Ottawa
Fundersnot available
KeywordsEinstein relationNernst equationElectrophoresisDiffusionField (mathematics)ChemistryAnalytical Chemistry (journal)Materials scienceChromatographyPhysicsThermodynamicsPhysical chemistryMathematics

Abstract

fetched live from OpenAlex

In this article, we examine the low-field electrophoretic migration of infinitely small analytes in dilute sieving media made of nonconducting gel fibers. Using an Ogston obstruction model, we show that the electrophoretic mobility is not affected by the presence of curved field lines. In other words, the Nernst-Einstein relation between the mobility and the diffusion coefficient is valid regardless of the electrical properties of the gel fibers. Although this finding may greatly simplify the development of obstruction models of electrophoretic sieving, it also represents a critical test for any analytical or computational approach.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.001
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: Theoretical or conceptual
GenreCandidate signal: Empirical · Consensus signal: none
Teacher disagreement score0.003
Threshold uncertainty score0.006

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.001
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.001
Bibliometrics0.0000.000
Science and technology studies0.0010.002
Scholarly communication0.0010.002
Open science0.0010.001
Research integrity0.0030.001
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.012
GPT teacher head0.243
Teacher spread0.232 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designTheoretical or conceptual
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations25
Published2001
Admission routes1
Has abstractyes

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