Polyaniline Binder for Functionalized Acetylene Black: A Hybrid Material for Supercapacitor
Bibliographic record
Abstract
Polyaniline-doped with functionalyzed acetylene black material has been successfully synthesized and used as an electrode material in supercapacitor, wherein, this material contributes both pseudocapacitative (PC) and electrical double layer capacitative (EDLC) behaviour. Functionalization of acetylene black (AB) has been carried out and used as dopant for THF soluble polyaniline base (PANI) to prepare PANI-functionalized acetylene black (PANI-FAB). Formation of FAB and PANI-FAB was confirmed with the help of FT-IR and XPS study. Functionalization of AB results in agglomerated FAB and doping with PANI results in agglomerated fibrous PANI-FAB, as compared to fibrous AB. High thermal stability of AB decreases on functionalization and again slightly increases for PANI-FAB. Functionalization of AB also results good bonding effect with PANI, where PANI acts as both PC and binder, instead of the higher amounts of binder (PVdF > 30 wt%) that are normally needed to hold AB. Electrochemical studies of FAB and PANI-FAB materials were carried out by cyclic voltammetric and electrochemical impedance spectroscopic methods. PANI-FAB supercapacitor cell shows capacitance of 132 Fg 1 for 0.3 Ag 1 current density with very low charge-transfer resistance and low time constant.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.005 | 0.002 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.001 | 0.000 |
| Scholarly communication | 0.001 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.005 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".