Properties of aminosilane precursors for the preparation of Si-C-N films
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Bibliographic record
Abstract
R n Si(NEt2)4 − n aminosilanes have been synthesized by reacting the R n SiCI4 − n (R = H, CH3; n = 1, 2) organylchlorosilanes with diethylamine. Using IR, UV, and NMR (1H, 13C, and 29Si) spectroscopies and elemental analysis, we have identified the reaction products and determined their spectroscopic characteristics. Vapor pressure measurements have been used to determine the saturated vapor pressure as a function of temperature and calculate the thermodynamic characteristics of vaporization. Thermodynamic modeling of chemical vapor deposition processes has been performed with the aim of predicting the phase composition of the deposit as a function of the nature of the precursor and process conditions.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.004 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it