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Record W1998378854 · doi:10.1063/1.3417385

Conformation of a tethered polymer in a leaky nanocavity

2010· article· en· W1998378854 on OpenAlexafffund
Issei Nakamura, An‐Chang Shi

Bibliographic record

VenueThe Journal of Chemical Physics · 2010
Typearticle
Languageen
FieldEngineering
TopicNanopore and Nanochannel Transport Studies
Canadian institutionsMcMaster University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsChain (unit)PolymerRandom walkIdeal (ethics)Random coilCrossoverChemical physicsMaterials scienceChemistryPhysicsCrystallographyMathematicsQuantum mechanicsNuclear magnetic resonanceComputer science

Abstract

fetched live from OpenAlex

The conformation of an ideal polymer chain confined in a box with a D x D hole is studied by N-step random walk simulations. For a polymer chain tethered inside the box, three conformational states are observed when the chain length is increased. For short chains the polymer assumes "mushroom" configurations. Increasing the chain length leads to a state in which the polymer fills the box. When the chain is long enough, the polymer escapes from the box, assuring an overall random walk state. Probability distributions of the free end and end-to-end distance are used to characterize polymer conformations. The escape transition is determined by the disappearance of the bimodal feature in the end-to-end probability density function. A crossover of the free energy difference between the confined and escaped states signals an escape transition analogous to the coil-globule transition of a free ideal chain.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.005
Threshold uncertainty score0.009

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0010.001
Open science0.0000.000
Research integrity0.0010.000
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.007
GPT teacher head0.203
Teacher spread0.195 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations0
Published2010
Admission routes2
Has abstractyes

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