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Record W1998498743 · doi:10.1002/cjce.20198

Relationship between sound pressure and reaction rate in sonochemical reaction

2009· article· en· W1998498743 on OpenAlexvenueno aff
Yasuhiko Takuma, Shigeru Kato, Toshinori Kojima

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2009
Typearticle
Languageen
FieldMaterials Science
TopicUltrasound and Cavitation Phenomena
Canadian institutionsnot available
Fundersnot available
KeywordsReaction rate constantReaction rateChemistrySound (geography)NitrophenolConstant (computer programming)Degradation (telecommunications)Linear relationshipRecovery rateSound pressurePosition (finance)ThermodynamicsKineticsOrganic chemistryAcousticsChromatographyCatalysisMathematicsComputer sciencePhysicsStatistics

Abstract

fetched live from OpenAlex

Abstract Relationship between sound pressure in a sonochemical reactor and degradation rate of organic compounds, p ‐chlorophenol and p ‐nitrophenol, was investigated. Reaction rates were analyzed as first‐order reaction. As a result, linear relationship was shown for each compound. Slope indicating the first reaction rate constant was remarkably affected by the position of the reaction flask. The sound pressure profile was measured and the relationship between the averaged pressure in a flask and the rate constant was shown. The relation was found to be remarkably different between the two. The threshold values were observed as 67kPa for p ‐chlorophenol and 22kPa for p ‐nitrophenol, respectively. From these results, it was shown that nature of compounds affects the dependency on sound pressure.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.591
Threshold uncertainty score0.214

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.218
Teacher spread0.202 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2009
Admission routes1
Has abstractyes

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