Dissociation energy of ekaplutonium fluoride E126F: The first diatomic with molecular spinors consisting of g atomic spinors
Bibliographic record
Abstract
Our ab initio all-electron fully relativistic Dirac-Fock (DF) and nonrelativistic (NR) Hartree-Fock (HF) self-consistent field (SCF) calculations predict the superheavy diatomic ekaplutonium fluoride E126F to be bound with the calculated dissociation energy of 7.44 and 10.46 eV at the predicted E126-F bond lengths of 2.03 and 2.18 Angstroms, respectively. The antibinding effects of relativity to the dissociation energy of E126F are approximately 3 eV. The predicted dissociation energy with both our NR HF and relativistic DF SCF wave functions is fairly large and is comparable to that for very stable diatomics. This is the first case, where in a diatomic, an atom has g orbital (l = 4) occupied in its ground state electronic configuration and such superheavy diatomics would have occupied molecular spinors (orbitals) consisting of g atomic spinors (orbitals). This opens up a whole new field of chemistry where g atomic spinors (orbitals) may be involved in electronic structure and chemical bonding of systems of superheavy elements with Z> or =122.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".