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Record W2000605844 · doi:10.1002/mats.200600024

Magnetic Field‐Induced Shape Transitions in Multiphase Polymer‐Liquid Crystal Blends

2006· article· en· W2000605844 on OpenAlexafffund
Susanta Das, Alejandro D. Rey

Bibliographic record

VenueMacromolecular Theory and Simulations · 2006
Typearticle
Languageen
FieldMaterials Science
TopicLiquid Crystal Research Advancements
Canadian institutionsMcGill University
FundersNatural Sciences and Engineering Research Council of CanadaSchweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
KeywordsLiquid crystalAnchoringMaterials sciencePhase diagramCondensed matter physicsPhase (matter)Texture (cosmology)Magnetic fieldField strengthAnisotropyOpticsChemistryPhysicsOptoelectronics

Abstract

fetched live from OpenAlex

Abstract Summary: This paper presents a computational study of phase separation‐phase ordering‐texturing in blends of polymer coils and rod‐like nematic liquid crystals under the presence of magnetic fields, using an extended version of the Matsuyama‐Evans‐Cates model ( Phys. Rev. E 2000 , 61 , 2977). This work demonstrates that demixing in these blends leads to droplet morphologies with tunable droplet shapes and director textures. In contrast to filled nematics, where solids are suspended in a nematic liquid crystal matrix, demixing in coil‐mesogenic rods blends leads to nematic emulsions, in which the deformable viscoelastic polymer drops are suspended in a nematic matrix. Under strong anchoring conditions, the imposition of a magnetic field leads to a director re‐orientation that due to strong anchoring produces a droplet shape change. Magnetic field‐induced shape transitions in these blends are shown to be second order with a finite critical field threshold that diverges as anchoring strength vanishes. A morphological‐texture diagram summarizes the magnetic field‐anchoring conditions that promote anisotropic shapes. This work presents additional material processing routes to design and control bi‐phasic morphologies in polymer‐liquid crystal blend. Computed morphology phase diagram in terms of magnetic field strength Λ M and anchoring strength. Λ ϕQ . magnified image Computed morphology phase diagram in terms of magnetic field strength Λ M and anchoring strength. Λ ϕQ .

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.023
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.278
Teacher spread0.268 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations11
Published2006
Admission routes2
Has abstractyes

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