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Record W2001062442 · doi:10.1021/jp204249j

Colloidal CuInSe<sub>2</sub> Nanocrystals in the Quantum Confinement Regime: Synthesis, Optical Properties, and Electroluminescence

2011· article· en· W2001062442 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueThe Journal of Physical Chemistry C · 2011
Typearticle
Languageen
FieldMaterials Science
TopicQuantum Dots Synthesis And Properties
Canadian institutionsUniversity of VictoriaUniversity of Toronto
Fundersnot available
KeywordsPhotoluminescenceNanocrystalElectroluminescenceMaterials scienceQuantum dotOptoelectronicsLight-emitting diodeStoichiometryNanoparticleColloidNanotechnologyLayer (electronics)ChemistryPhysical chemistry

Abstract

fetched live from OpenAlex

Photoluminescent, near-stoichiometric colloidal CuInSe 2 nanocrystals are synthesized in large batches and with good colloidal quality. An organometallic method is used with a moderate reaction temperature (≤200 °C) to produce CuInSe 2 nanocrystals with size-tunable photoluminescence spectra ranging from ∼600 to ∼850 nm. Two-dimensional photoluminescence excitation–emission maps are reported for the CuInSe 2 nanocrystals, highlighting the size-tunable excitonic features. Type I heterostructured CuInSe 2 /ZnS nanocrystals are prepared and purified. They are found to have absolute photoluminescence quantum yields up to ∼26%. The potential to use CuInSe 2 /ZnS core/shell nanocrystals as a potential low toxicity active layer in light-emitting diodes is demonstrated by fabricating electroluminescent devices.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.002
Threshold uncertainty score0.386

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.001
Scholarly communication0.0000.000
Open science0.0010.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.029
GPT teacher head0.208
Teacher spread0.179 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it