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Record W2002194155 · doi:10.1021/ie0011425

Permeability, Selectivity, and Testing of Hydrogen Diffusion Membranes Suitable for Use in Steam Reforming

2001· article· en· W2002194155 on OpenAlexafffund
Kai Jarosch, Hugo de Lasa

Bibliographic record

VenueIndustrial & Engineering Chemistry Research · 2001
Typearticle
Languageen
FieldChemical Engineering
TopicCatalysts for Methane Reforming
Canadian institutionsWestern University
FundersNatural Sciences and Engineering Research Council of Canada
KeywordsHydrogenPermeationMembraneChemical engineeringPermeability (electromagnetism)Steam reformingSelectivityPalladiumArgonCatalysisMethaneMaterials scienceChemistryHydrogen productionOrganic chemistry

Abstract

fetched live from OpenAlex

Three composite hydrogen-permeable membranes were produced by the electroless deposition of palladium on macroporous Inconel. The permeability and selectivity for hydrogen to argon was assessed over the range 750−850 °C using a 156-μm-thick membrane. The permeability coefficient was 1.874 × 10 -6 mol/(m s kPa 0.5 ), with an activation energy of 22.6 kJ/mol. Membranes produced by the electroless technique exhibited hydrogen/argon molar selectivities in the range (336−1187):1. Two membranes were used to assess the effect of hydrogen permeation on the conversion of methane over a 20 wt % Ni/α-alumina catalyst in a CREC riser simulator used to model a fast fluidized bed. Hydrogen permeation from the reactor produced conversions in excess of those attainable at equilibrium and favorably modified the composition of the synthesis gas.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame machine prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.002
Version: metacan-v3-hybrid-931329e0061cValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.001
Threshold uncertainty score0.005

Distilled classifier scores by category (both heads)

CategoryCodexGemma
Metaresearch0.0010.002
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0000.000
Research integrity0.0010.001
Insufficient payload (model declined to judge)0.0010.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.127
GPT teacher head0.331
Teacher spread0.204 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations24
Published2001
Admission routes2
Has abstractyes

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