<title>Variable porous structure of laser-ablated silicon nanocluster films and its influence on photoluminescence properties</title>
Bibliographic record
Abstract
Si/SiO<SUB>x</SUB> films were fabricated by Pulsed Laser Ablation from a silicon target in a residual gas. The films were crystalline with minimal grain size of 2-4 nm and had a porous morphology. The film structure was found to be extremely sensitive to deposition conditions with porosity depending on the gas pressure during the deposition. In particular, the increase of helium pressure from 0.2 to 4 Torr in different depositions led to a gradual porosity (P) increase from 10% to 95%. The porosity increase was accompanied by a slight increase of mean crystal size in the deposit. It has been established that photoluminescence (PL) properties were different for films with different porosities. For low porous films (P < 40 %), we observed PL signals with peak energies between 1.6 and 2.12 eV depending on helium deposition pressure. In contrast, PL properties of highly porous films (P > 40%) were mainly determined by post-deposition oxidation phenomena. They led to an enhancement of PL bands around 1.6-1.7 eV and 2.2-2.3 eV, which were independent of deposition conditions. Similar 2.2-2.3 eV signals were observed after strong film oxidation through a thermal annealing of films in air or through a silicon ablation in oxygen-containing atmosphere. Mechanisms of film formation and PL origin are discussed.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".