Dark State Illuminated: Infrared Spectrum and Inverted Torsional Structure of the<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="italic">ν</mml:mi></mml:mrow><mml:mrow><mml:mn>11</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>Out-of-Plane<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi>CH</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>-Rocking Mode of Methanol
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
The nu(11) out-of-plane CH3-rocking band of methanol, one of the last fundamentals remaining en route to full vibrational description of this prototype internal rotor, has been identified in the Fourier transform spectrum of CH3OH in the 1150 cm(-1) region. The nu(11) torsional energy pattern is found to be inverted, the first such discovery for a bending state and an important pointer to potential generality of this phenomenon for the whole class of threefold internal rotor molecules. Level-crossing resonances giving transfer channels for intramolecular vibrational energy redistribution (IVR) have been found, and new insights are reported for far-infrared laser emission involving nu(11) levels.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.003 | 0.004 |
| Meta-epidemiology (narrow) | 0.003 | 0.005 |
| Meta-epidemiology (broad) | 0.001 | 0.006 |
| Bibliometrics | 0.001 | 0.003 |
| Science and technology studies | 0.003 | 0.005 |
| Scholarly communication | 0.003 | 0.003 |
| Open science | 0.006 | 0.005 |
| Research integrity | 0.005 | 0.005 |
| Insufficient payload (model declined to judge) | 0.729 | 0.002 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it