Nanostructured Polymer Films with Liquid Inclusions. 2. Material Morphology and Properties
Bibliographic record
Abstract
Three-layer core−shell latex particles with fluid cores were used for the preparation of a polymeric nanostructured material. The fluid cores were synthesized from the low glass transition temperature core-forming polymer (CFP) covalently labeled with a fluorescent dye. The CFP was encapsulated with a thin rigid shell of shell-forming polymer 1 (SFP-1). The second shell was synthesized from the shell-forming polymer 2 (SFP-2) on the surface of the bilayer particles. The specific relationship between the glass transition temperatures, T g 's, of the polymers incorporated into the core−shell particles was T g (CFP) < T g (SFP-2) < T g (SFP-1). Nanocomposite polymeric films were obtained following heat processing of the arrays of core−shell particles at annealing temperature, T g (SFP-2) < T ann < T g (SFP-1). The morphology of the nanostructured material was studied by examining the distribution of the fluorescent dye in the polymer film. Various factors providing sharp modulation in optical properties of the composite films were examined and discussed.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".