Periodic Mesoporous Silica-Based Organic−Inorganic Nanocomposite Materials
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
The area of periodic mesoporous materials prepared by cooperative assembly in the presence of amphiphile molecules underwent dramatic growth. Among the silica-based materials, many types may be regarded as ordered organic−inorganic nanocomposites. These were divided into five categories: (i) noncalcined amphiphile/silica mesophases, (ii) mesoporous silicas with organically modified surfaces, (iii) expanded mesoporous silicas, (iv) mesoporous organosilicates, and (v) mesoporous silica with occluded organic materials such as polymers. The diversity of such nanocomposites created new potential opportunities in materials sciences, catalysis, separation, and environmental remediation. These applications involved the development of new chemistry not only within the confined pores and channels but also on functionalized surfaces as well as within the channels walls. The current review deals with recent progress in the synthesis, characterization, and applications of each of these types of periodic mesoporous silica-based hybrid materials.
Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.096 | 0.001 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it