Copoly(Aryl Ether)s Containing 1,10‐Phenanthroline Moieties
Why this work is in the frame
A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.
Bibliographic record
Abstract
Abstract Poly(aryl ether)s were synthesized by reaction of 4,7‐dichloro‐3,8‐diphenyl‐1,10‐phenanthroline and 4,7‐dichloro‐2,9‐dimethyl‐1,10‐phenanthroline with bisphenol A (BPA) in the presence of potassium carbonate in N,N‐dimethylacetamide or N‐methylpyrrolidinone. High molecular weight homopolymers could not be prepared because of the insolubility of the polymers resulting in premature precipitation from the reaction mixture. Soluble, high molecular weight copolymers were readily prepared containing up to 70 mol% of the 1,10‐phenanthroline moieties. The copolymers were all highly fluorescent with blue emission. Keywords: Copoly(aryl ether)sPhenanthrolineFluorescence Acknowledgments This research was funded by the Natural Sciences and Engineering Research Council of Canada.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.004 | 0.001 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.001 |
| Scholarly communication | 0.000 | 0.001 |
| Open science | 0.001 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.003 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it