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Record W2005748778 · doi:10.1002/cjce.21765

Simulation of pellet model with multicomponent mass diffusion closure using least squares spectral element solution method

2013· article· en· W2005748778 on OpenAlexvenueno aff
Kumar R. Rout, Hugo A. Jakobsen

Bibliographic record

VenueThe Canadian Journal of Chemical Engineering · 2013
Typearticle
Languageen
FieldChemical Engineering
TopicCatalysts for Methane Reforming
Canadian institutionsnot available
FundersNorges Forskningsråd
KeywordsDiffusionPelletMass fluxDiffusion processChemistryFlux (metallurgy)Least-squares function approximationClosure (psychology)Process (computing)MechanicsThermodynamicsMathematicsMaterials sciencePhysicsComputer scienceStatistics

Abstract

fetched live from OpenAlex

Abstract Mass‐ and mole‐based pellet models have been solved using least‐squares formulation to describe the evolution of species composition, pressure, velocity, total concentration and mass diffusion fluxes in porous pellets for the steam methane reforming (SMR) process. The objective of this work has been to compare the mass‐ and mole‐based diffusion flux models, convection and fluid velocity for the SMR process using the least‐squares spectral element method (LS‐SEM). The diffusion–reaction problems are computationally intensive, requiring efficient numerical methods for dealing with them. This paper presents formulation and algorithm of LS‐SEM for solving multicomponent mass diffusion pellet models. The mass diffusion flux is described according to the rigorous Maxwell Stefan model. This flux may be defined either with molar‐ or mass‐averaged velocities. The effectiveness factors have been calculated for the SMR process and compared with the literature data. The model evaluations revealed that: ‐ The least‐squares method is well‐suited for solving the multicomponent mass diffusion pellet models for the SMR process, achieving exponential convergence. ‐ Molar‐ and mass‐based pellet models do not give fully identical results for the SMR process, since the pellet model is not completely consistent.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Simulation or modeling · Consensus signal: Simulation or modeling
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.265
Threshold uncertainty score0.602

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.016
GPT teacher head0.231
Teacher spread0.216 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designSimulation or modeling
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations2
Published2013
Admission routes1
Has abstractyes

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