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Record W2005903909 · doi:10.1021/la703402b

A New Model System for Diffusion NMR Studies of Concentrated Monodisperse and Bidisperse Colloids

2008· article· en· W2005903909 on OpenAlexaff
Swomitra Palit, Anand Yethiraj

Bibliographic record

VenueLangmuir · 2008
Typearticle
Languageen
FieldPhysics and Astronomy
TopicNMR spectroscopy and applications
Canadian institutionsMemorial University of Newfoundland
Fundersnot available
KeywordsColloidDispersityDiffusionSuspension (topology)ChemistryPhase (matter)Chemical physicsChemical engineeringAnalytical Chemistry (journal)Materials scienceThermodynamicsChromatographyPhysical chemistryPolymer chemistryOrganic chemistryPhysics

Abstract

fetched live from OpenAlex

A method to prepare monodisperse and simultaneously NMR-visible and fluorescent colloidal particles is described, and a systematic approach to obtain spectrally resolved diffusion coefficient for every component in a monodisperse colloidal suspension is presented. We also prepared bidisperse colloidal suspensions, where each colloid component has a distinct NMR spectral signature, and obtained the diffusion coefficients of both colloid species simultaneously in concentrated colloidal suspensions, with volume fractions between 20 and 50%. The colloidal model system developed in this work enables the study of colloidal phase behavior in binary mixtures for different number and size ratios.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Theoretical or conceptual · Consensus signal: none
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.694
Threshold uncertainty score0.271

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.030
GPT teacher head0.332
Teacher spread0.302 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designTheoretical or conceptual
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations6
Published2008
Admission routes1
Has abstractyes

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