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Record W2006480128 · doi:10.3402/tellusb.v56i3.16432

Annual time-series of total filterable atmospheric mercury concentrations in the Arctic

2004· article· en· W2006480128 on OpenAlex
Julia Lu, W. H. Schroeder

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.
aboutThe title or abstract carries a Canadian signal from the geographic lexicon.

Bibliographic record

VenueTellus B · 2004
Typearticle
Languageen
FieldEnvironmental Science
TopicMercury impact and mitigation studies
Canadian institutionsEnvironment and Climate Change CanadaToronto Metropolitan University
Fundersnot available
KeywordsSunriseMercury (programming language)Environmental scienceArcticPolar nightElemental mercuryEnvironmental chemistryMERCUREPolarAtmospheric chemistryAtmospheric sciencesChemistryMeteorologyOzoneAnalytical Chemistry (journal)GeologyOceanographyGeography

Abstract

fetched live from OpenAlex

Total atmospheric mercury (TAM) is operationally defined as the sum of gaseous elemental mercury (GEM), gaseous oxidized inorganic mercury (GOIM), which is also called reactive gaseous mercury (RGM), and total filterable mercury (TFM). An annual weekly-integrated time-series of TFM concentrations in ambient air at Alert, Nunavut, Canada from March 1998 to March 1999 is reported in this paper. The observed TFM concentrations ranged from 0 to 0.37 ng m−3 with the highest value occurring in the spring after polar sunrise and the lowest in summer. The average values for the four seasons are 0.086 (March—May), 0.00085 (June—August), 0.0015 (September—November) and 0.013 ng m−3 (December 1998–February 1999) respectively. This pattern is anti-correlated to that of GEM concentration observed at the same location. The GOIM concentration, calculated using the equation [GOIM]=[TAM]−[GEM]−[TFM], is also anti-correlated with GEM concentration. The annual time-series of the TFM operational blank values shows the same temporal pattern as the TFM concentration, with values ranging from 0.00 to 0.011 ng m−3. These results confirm that, in the polar regions, GEM oxidation and atmospheric deposition of mercury occur mainly in the 3-month period after polar sunrise. Incisive laboratory and field experiments are needed to either confirm or rule out the springtime GEM oxidation/conversion mechanisms proposed in this paper.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesInsufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Observational · Consensus signal: Observational
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.551
Threshold uncertainty score0.999

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0000.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.010
GPT teacher head0.228
Teacher spread0.218 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it