Optical Zeeman effect measurements on isolated and ferromagnetically coupled Nd<sup>3+</sup>ions in weakly doped YVO<sub>4</sub>crystals: evidence for lack of crystal field perturbations in ion pair interactions
Bibliographic record
Abstract
Optical Zeeman effect measurements are performed at liquid helium temperature on Nd3+ ions in weakly doped YVO4 crystals in the range 11 350-11 390 cm-1 of the 4F3/2→ 4I9/2 neodymium transitions. This study provides confirmation that the concentration dependent satellite lines accompanying the optical transitions are due to ferromagnetically coupled pairs of Nd3+ ions in undistorted Y3+ sites of D2d point site symmetry. Nonlinear Zeeman splittings are observed in the range of experimental magnetic fields. These splittings are compared with those simulated from crystal field calculations by introducing the Zeeman Hamiltonian into the secular determinant before diagonalization. A reasonably good agreement between the calculated and experimental g-values is obtained, confirming that the exchange coupled neodymium pairs experience no crystal field perturbations.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".