Dynamical quenching of laser-induced dissociations of diatomic molecules in intense infrared fields: Effects of molecular rotations and misalignments
Bibliographic record
Abstract
The dynamical dissociation quenching (DDQ) effect is a new mechanism for laser-induced vibrational trapping of molecules in the infrared (IR) spectral range. Previously demonstrated for one-dimensional, prealigned diatomic molecules [see F. Châteauneuf, T. Nguyen-Dang, N. Ouellet, and O. Atabek, J. Chem. Phys. 108, 3974 (1998)], the effect was shown to result from a proper synchronization of the molecular motions with the oscillations of the laser electric field. The present paper explores the influence of rotations and misalignment of the molecular system on the DDQ effect. To this end, the two-dimensional (radial and angular) wave-packet dynamics of the H2+ and HD+ molecular ions are considered in an intense IR laser field starting from two types of initial angular distributions: The first type of distributions is appropriate for a field-free, pure angular momentum eigenstate and denotes typically an initially nonaligned, nonoriented molecule. The second type denotes a more or less well aligned and/or oriented initial condition, and is described by an angular width Δ which is considered a parameter in terms of which the efficiency of the DDQ effect are monitored. We demonstrate that the DDQ effect remains efficient whenever a proper compromise is achieved between angular localization and angular-momentum (action) minimization. From the detailed analysis of the time-resolved dynamics, a time scale is also estimated for the molecule-field synchronization process which underlies the DDQ effect. An ultrafast laser-induced rotational-electronic energy transfer is found to compete with the DDQ effect, in the case the initial rotational state denotes an almost perfect alignment and/or orientation situation.
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How this classification was reachedexpand
Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.000 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one teacher head, not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".