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Record W2010928605 · doi:10.1081/wct-200038066

Sample Contamination in Analysis of Wood Pulp Fibers with X‐ray Photoelectron Spectroscopy

2004· article· en· W2010928605 on OpenAlexaff
Kecheng Li, Douglas W. Reeve

Bibliographic record

VenueJournal of Wood Chemistry and Technology · 2004
Typearticle
Languageen
FieldMaterials Science
TopicElectron and X-Ray Spectroscopy Techniques
Canadian institutionsUniversity of TorontoUniversity of New Brunswick
Fundersnot available
KeywordsX-ray photoelectron spectroscopyContaminationChemistryPulp (tooth)LigninCelluloseFOIL methodKraft processKraft paperComposite materialMaterials scienceChemical engineeringOrganic chemistry

Abstract

fetched live from OpenAlex

Abstract Contamination of wood pulp fiber samples by the ambient in the x‐ray photoelectron spectroscopy (XPS) analysis was investigated. Various control samples, including platinum foil, cellophane, cellobiose, rayon, cotton, and fully bleached wood pulp fibers, were used for identification and characterization of the contamination sources. It has been found that contaminating material on wood fiber surfaces contains both carbon and oxygen and is responsible for the discrepancy between the true elemental composition of wood pulp fiber surfaces and the composition determined by XPS. A physical model of the contamination has been proposed which allows compensation for the contamination in quantitative analysis of surface lignin by XPS.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

How this classification was reachedexpand

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.000
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesnone
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Bench or experimental · Consensus signal: Bench or experimental
GenreCandidate signal: Empirical · Consensus signal: Empirical
Teacher disagreement score0.009
Threshold uncertainty score0.524

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0000.000
Meta-epidemiology (narrow)0.0000.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.001
Science and technology studies0.0000.000
Scholarly communication0.0000.000
Open science0.0000.000
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0000.000

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.004
GPT teacher head0.239
Teacher spread0.235 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it

Classification

machine, unvalidated

Machine predicted; a candidate call from one teacher head, not a consensus.

The models applied no category: nothing in the taxonomy fit this work.
Study designBench or experimental
Domainnot available
GenreEmpirical

How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".

Quick stats

Citations22
Published2004
Admission routes1
Has abstractyes

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