Large Pressure-Induced Red Shift of the Luminescence Band Originating from Nonstacked Square-Planar [Pt(SCN)<sub>4</sub>]<sup>2</sup><sup>-</sup>in a Novel Trimetallic Complex
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Bibliographic record
Abstract
Luminescence of the novel trimetallic complex {Pt(SCN)2[(mu-SCN)Mn(NCS)(bipy)2]2} originates from a d-d transition of the square-planar [Pt(SCN)4]2- moiety. The band maximum shows a red shift of -99 cm(-1) kbar(-1) under external pressure up to 32 kbar at room temperature. This red shift is comparable to values for crystals where Pt-Pt interaction between stacked complexes is enhanced by pressure, but the crystal structure for the trimetallic complex shows that no metal-metal interaction can occur.
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Full frame distilled prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.
Codex and Gemma teacher scores by category
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.001 | 0.001 |
| Meta-epidemiology (narrow) | 0.001 | 0.001 |
| Meta-epidemiology (broad) | 0.001 | 0.000 |
| Bibliometrics | 0.000 | 0.001 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.002 | 0.000 |
| Research integrity | 0.000 | 0.001 |
| Insufficient payload (model declined to judge) | 0.002 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it