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Record W2011393615 · doi:10.1039/b704248p

Capillary models for liquid crystal fibers, membranes, films, and drops

2007· review· en· W2011393615 on OpenAlex

Why this work is in the frame

A frame that forgets how it found something cannot be audited. These are the routes that admitted this work.

affAt least one author lists a Canadian institution in the pinned OpenAlex snapshot.

Bibliographic record

VenueSoft Matter · 2007
Typereview
Languageen
FieldMaterials Science
TopicLiquid Crystal Research Advancements
Canadian institutionsMcGill University
Fundersnot available
KeywordsLiquid crystalCapillary actionMaterials scienceWettingSoft matterContact angleChemical physicsAnchoringMembraneElectric fieldNanotechnologyComposite materialColloidChemistryOptoelectronics

Abstract

fetched live from OpenAlex

This paper presents an overview of the capillary modeling science of nematic liquid crystals and its applications to the stability, structure, and shape of films, membranes, fibers, and drops. Liquid crystals are anisotropic viscoelastic materials possessing long range orientational order, and hence these models are relevant to the capillary science of anisotropic soft matter. A systematic multiscale approach is used to derive the equations that govern the shape of interfaces and contact lines. These shape equations generalize the surface Laplace and the contact line Neuman equations by introducing long range orientational order, gradient elasticity, surfactant adsorbants, magnetic and electric fields. The thermodynamics of capillary systems is used to reveal novel cross-effects such as adsorption-driven shape changes of surfaces and contact lines. The capillary models are used to analyze the structure and stability of films, membranes, fibers, and drops, of direct relevance to the processing and performance of structural and functional liquid crystals. Novel soft materials and mechanisms analyzed in this paper include: (1) stabilization of freely-suspended nematic films by orientation and molecular order heterogeneities, (2) orientational defects in polymer dispersed liquid crystals films, shown to originate from surface anchoring transitions, (3) electric field-induced curvature in membranes for sensor and actuator applications, (4) new helical morphologies of thin nematic filaments driven by strong interfacial anchoring, (5) tunable partial wetting through contact angle modification gradient and anchoring elasticity, (6) liquid crystal nanoemulsion shape control through anchoring effects, and (7) magnetic shaping in liquid crystal colloids. Readily accessible applications to biological liquid crystal materials and processes indicate that capillary modeling science will be a most active area of research in the very near future.

Fetched live from OpenAlex and de-inverted. Abstracts are not stored in this database: the inverted indexes are 8.6 GB of the frame’s 9.3 GB of text, and the host has 13 GB free.

Full frame distilled prediction

Teacher imitation

Not calibrated prevalence, not ground truth. Human validation pending. Learned from the 10,348 direct Codex labels and 10,348 direct Gemma labels. Candidate is the union of thresholded teacher heads; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels or direct frontier model labels.

metaresearch head score (Codex)0.001
metaresearch head score (Gemma)0.000
Version: codex-gemma-dda1882f352aValidation status: machine_predicted_unvalidated
Candidate categoriesMeta-epidemiology (narrow), Insufficient payload (model declined to judge)
Consensus categoriesnone
DomainCandidate signal: none · Consensus signal: none
Study designCandidate signal: Not applicable · Consensus signal: none
GenreCandidate signal: Review · Consensus signal: Review
Teacher disagreement score0.744
Threshold uncertainty score1.000

Codex and Gemma teacher scores by category

CategoryCodexGemma
Metaresearch0.0010.000
Meta-epidemiology (narrow)0.0010.000
Meta-epidemiology (broad)0.0010.000
Bibliometrics0.0000.000
Science and technology studies0.0000.000
Scholarly communication0.0000.001
Open science0.0010.001
Research integrity0.0000.000
Insufficient payload (model declined to judge)0.0020.001

Machine scores (provisional)

The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.

Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.

Opus teacher head0.062
GPT teacher head0.352
Teacher spread0.290 · how far apart the two teachers sit on this one work
Validation statusscore_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from it