Investigating the Stability Mechanism of Water-in-Diluted Bitumen Emulsions through Isolation and Characterization of the Stabilizing Materials at the Interface
Bibliographic record
Abstract
In oil sand industry, formation of a stable salty water-in-diluted bitumen emulsion poses a serious corrosion problem at the bitumen upgrading plant. Previous studies indicated the presence of a “critical concentration” of bitumen in the emulsion, above which the oil−water interface is flexible and the water-in-diluted bitumen emulsion is stable, but below which the interface becomes rigid and the emulsion is unstable. The cause of this critical concentration was investigated through isolation and characterization of the interfacial material from the emulsions both below and above the critical concentration. The analytical data showed that, in heptane/toluene(1:1)-diluted bitumen emulsions, the flexible interfacial film is composed of a mixture of asphaltene and carboxylic salts with a combined H/C ratio of 1.32 while the rigid interfacial film is composed of asphaltene alone with a H/C ratio of 1.13. The carboxylic salts are water insoluble and are likely sodium naphthenates containing >20 carbons. The presence of sodium naphthenates might hinder the conformational change of asphaltene at the interface, necessary for rigid film formation.
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How this classification was reachedexpand
Full frame machine prediction
Teacher imitationNot calibrated prevalence, not ground truth. Human validation pending. The Gemma side is a direct model label for every work in the frame, read from the title-only record. The Codex side is a classifier learned from the 10,348 direct Codex labels and calibrated to design-weighted sample rates; fields without enough sample support carry no Codex call. Candidate is the union of the two sides; consensus is their intersection. These outputs are machine_predicted_unvalidated and are not human labels.
Distilled classifier scores by category (both heads)
| Category | Codex | Gemma |
|---|---|---|
| Metaresearch | 0.000 | 0.000 |
| Meta-epidemiology (narrow) | 0.000 | 0.000 |
| Meta-epidemiology (broad) | 0.000 | 0.000 |
| Bibliometrics | 0.000 | 0.000 |
| Science and technology studies | 0.000 | 0.000 |
| Scholarly communication | 0.000 | 0.000 |
| Open science | 0.000 | 0.000 |
| Research integrity | 0.000 | 0.000 |
| Insufficient payload (model declined to judge) | 0.001 | 0.000 |
Machine scores (provisional)
The two teacher heads of the student model, read on this work. A score orders the frame for review; it never asserts a category, and the validation status ships verbatim with every row.
Baseline scores from an immature model (maturity gate not passed, 7 training rounds). Scores rank; they never assert a category.
score_only:v0-immature-baseline · verbatim from the scoring run: score_only means the number may rank works, and no category label ships from itClassification
machine, unvalidatedMachine predicted; a candidate call from one source (direct Gemma or distilled Codex), not a consensus.
How this classification was reached, model by model and score by score, is at the end of the page under "How this classification was reached".